I think Natalya and Bond in 'GoldenEye' - something so outrageous yet heroic about it, literally thundering through a town against the odds to reach her and nothing will stop him. Pure Bond!
Which tie adjustment was far cooler for you from Pierce Brosnan....
After stopping the Russian soldiers in the tank in 'GoldenEye'
OR
Underwater in the Q-Boat during 'The World Is Not Enough'
??